Search results for "soil ga"
showing 10 items of 19 documents
Tectonic control over large-scale diffuse degassing in eastern Sicily (Italy)
2002
Eastern Sicily (southern Italy) is characterised by the presence of many natural gas emissions (mofettes, mud volcanoes). These gases are mostly carbon dioxide and methane, with minor amounts of helium, hydrogen, carbon monoxide and hydrocarbons. In this study, the extent and orientation of soil gas anomalies (He and CO2) were investigated on a wide area (approximately 110 km2) located just SW of Mt. Etna. From a structural point of view, this area lays on a typical foredeep–foreland system that marks the boundary between the southern part of the Eurasian plate and the northern part of the African plate in the central Mediterranean. No tectonic structure was revealed in this area by surface…
Anomalous soil CO 2 degassing in relation to faults and eruptive fissures on Mount Etna (Sicily, Italy)
1998
The relationships between soil gas emissions and both tectonic and volcano-tectonic structures on Mt. Etna have been studied. The investigation consisted of soil CO2 flux measurements along traverses orthogonal to the main faults and eruptive fissures of the volcano. Anomalous levels of soil degassing were found mainly in coincidence with faults, whereas only 49% of the eruptive fissures were found to produce elevated CO2 soil fluxes. This result suggests that only zones of strain are able to channel deep gases to the surface. According to this hypothesis, several previously unknown structures are suggested. Based on our geochemical data, new structural maps of different areas of Etna are p…
Diffuse soil gas emissions of gaseous elemental mercury (GEM) from hydrothermal-volcanic systems: An innovative approach by using the static closed-c…
2016
This study was aimed to test a new methodological approach to carry out measurements of gaseous elemental mercury (GEM) diffusively emitted from soils in hydrothermal-volcanic environments. This method was based on the use of a static closed-chamber (SCC) in combination with a Lumex® RA-915M analyzer that provides GEM measurements in a wide range of concentrations (from 2 to 50,000 ng m-3). Gas samples were collected at fixed time intervals from the SCC positioned on the ground (time-series samples). The Lumex® inlet port was equipped with a three-way Teflon valve allowing the free entrance of air through a carbon trap, in order to: (i) prevent disturbance to the Lumex® operative flow rate …
Effects of soil gas permeability and recirculation flux on soil CO2 flux measurements performed using a closed dynamic accumulation chamber
2009
Abstract Dynamic accumulation chamber methods have been extensively used to estimate the total output of CO2 released from active volcanic area. In order to asses the performance and reliability of a closed dynamic system several tests were carried out with different soil permeabilities and soil CO2 fluxes. A special device was used to create a constant one-dimensional CO2 flux through a soil column with a known permeability. Three permeabilities were investigated, ranging between 3.6 × 10− 2 and 3.5 × 10 μm2, as were several CO2 fluxes (ranging between 1.1 × 10− 6 and 6.3 × 10− 5 kg m− 2 s− 1). The results highlight that the accuracy of soil CO2 flux measurements strictly depends on the so…
Total CO2output from Vulcano island (Aeolian Islands, Italy)
2012
[1] Total CO2 output from fumaroles, soil gas, bubbling gas discharges and water dissolved gases discharged from the island, was estimated for Vulcano island, Italy. The CO2 emission from fumaroles from the La Fossa summit crater was estimated from the SO2 crater output, while CO2 discharged through diffuse soil emission was quantified on the basis of 730 measurements of CO2 fluxes from the soil of the island, performed by using the accumulation chamber method. The results indicate an overall output of ≅500 t day−1 of CO2 from the island. The main contribution to the total CO2 output comes from the summit area of the La Fossa cone (453 t day−1), with 362 t day−1 from crater fumaroles and 91…
CO2 output discharged from Stromboli Island (Italy)
2013
Abstract Total CO 2 output from soil gas and plume, discharged from the Stromboli Island, was estimated. The CO 2 emission of the plume emitted from the active crater was estimated on the basis of the SO 2 crater output and C/S ratio, while CO 2 discharged through diffuse soil emission was quantified on the basis of 419 measurements of CO 2 fluxes from the soil of the whole island, performed by using the accumulation chamber method. The results indicate an overall output of ≅ 416 t day − 1 of CO 2 from the island. The main contribution to the total CO 2 output comes from the summit area (396 t day − 1 ), with 370 t/day from the active crater and 26 t day − 1 from the Pizzo sopra La Fossa so…
CO2 degassing at La Solfatara volcano (Phlegrean Fields): Processes affecting and of soil CO2
2010
Abstract The soil CO2 degassing is affected by processes of isotope exchange and fractionation during transport across the soil, which can deeply modify the pristine isotope composition. This has been observed in the Solfatara volcano, upon a field survey of 110 points, where the CO2 flux was measured, together with temperature, CO2 concentration and oxygen and carbon isotopes within the soil. Furthermore, in some selected sites, the measurements were made at different depths, in order to analyze vertical gradients. Oxygen isotope composition appears controlled by exchange with soil water (either meteoric or fumarolic condensate), due to the fast kinetic of the isotopic equilibrium between …
Phytoscreening as an efficient tool to delineate chlorinated solvent sources at a chlor-alkali facility
2017
Chlorinated ethenes (CE) are among the most common volatile organic compounds (VOC) that contaminate groundwater, currently representing a major source of pollution worldwide. Phytoscreening has been developed and employed through different applications at numerous sites, where it was generally useful for detection of subsurface chlorinated solvents. We aimed at delineating subsurface CE contamination at a chlor-alkali facility using tree core data that we compared with soil data. For this investigation a total of 170 trees from experimental zones was sampled and analyzed for perchloroethene (PCE) and trichloroethene (TCE) concentrations, measured by solid phase microextraction gas chromato…
The summit part of Mount Etna revealed by High Resolution DC Electrical Resistivity Tomography coupled with complementary geophysical and soil gas te…
2016
Between 25 June and 13 July 2015 a very deep ERT profile (Pole-Dipole configuration, 40m spacingbetween electrodes and a remote electrode located at ~10km from the acquisition points) has been performedin the framework of the “MED-SUV” Project. Self-potential, soil gas concentrations (CO2, 222Rn, 220Rn, He,H2 and CH4) and soil temperature measurements were coupled to the ERT profile with a spacing of 20m(except for Rn: 40m). The NE-SW profile crossed Etnas summit craters in the middle of the 5720m ERTtotal length. Six roll along protocols of . of the dispositive (600m out of 2520m tot) have been carried outand, for the first time, a high resolution DC ERT profile reached the noticeable inve…
Soil gas prospection of He,222Rn and CO2: Vulcano Porto area, Aeolian Islands, Italy
1997
Abstract In March 1994, soil gases were sampled in the area of Vulcano Porto, on the island of Vulcano, using a grid of about 200 points/km 2 . Analysed gases were CO 2 , He and 222 Rn and, over a smaller area, H 2 S. Some of the samples were also analysed for the isotope composition of CO 2 C. Three anomalous CO 2 degassing areas were identified: Grotta dei Palizzi, the area near the Telephone Exchange, and the area near the beach fumaroles. The behaviour of He and 222 Rn is different in these 3 areas. The concentration of He is much lower than that of atmospheric He (down to −3950 ppb) in the isthmus, and only in the area near Grotta dei Palizzi does it have values significantly higher th…